Rotational spectrum H19F spin-spin and D-nuclear quadrupole coupling constants and molecular geometry of the sulphur dioxide and hydrogen fluoride dimer

Fillery-Travis, Annette and Legon, Anthony (1986) Rotational spectrum H19F spin-spin and D-nuclear quadrupole coupling constants and molecular geometry of the sulphur dioxide and hydrogen fluoride dimer. Journal of Chemical Physics, 85 (6) . pp. 3180-3186. ISSN 0021-9606 [Article] (doi:10.1063/1.451829)

Abstract

Through the determination of the spin-spin and quadrupole coupling constants it was possible to determine the dynamics of the hydrogen bonding within this dimer. Specifically the tunneling of the HF molecule between the lone-pairs of the adjacent oxygen atoms of the sulphur dioxide molecule.

Item Type: Article
Research Areas: A. > Work and Learning Research Centre
Item ID: 17449
Useful Links:
Depositing User: Annette Fillery-Travis
Date Deposited: 02 Sep 2015 09:54
Last Modified: 09 May 2017 11:32
URI: https://eprints.mdx.ac.uk/id/eprint/17449

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