Studies toward the synthesis of azadirachtin, part 2 : construction of fully functionalized ABCD ring frameworks and unusual intramolecular reactions induced by close-proximity effects

Nicolaou, K. C., Sasmal, Pradip K., Koftis, Theocharis V., Converso, Antonella, Loizidou, Erika, Kaiser, Florian, Roecker, A. J., Dellios, Constantinos C., Sun, Xiao-Wen and Petrovic, Goran (2005) Studies toward the synthesis of azadirachtin, part 2 : construction of fully functionalized ABCD ring frameworks and unusual intramolecular reactions induced by close-proximity effects. Angewandte Chemie International Edition, 44 (22). pp. 3447-3452. ISSN 1433-7851

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Abstract

The remarkable antifeedant agent and insecticide, azadirachtin (1), has, to date, escaped a total synthesis. The preparation of an advanced precursor has revealed some of the inner intricacies of this uniquely crowded and highly functionalized molecular architecture.

Item Type: Article
Research Areas: A. > School of Science and Technology > Natural Sciences
Item ID: 14365
Depositing User: Erika Loizidou
Date Deposited: 06 Mar 2015 10:11
Last Modified: 13 Oct 2016 14:32
URI: https://eprints.mdx.ac.uk/id/eprint/14365

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