Studies toward the synthesis of azadirachtin, part 2 : construction of fully functionalized ABCD ring frameworks and unusual intramolecular reactions induced by close-proximity effects

Nicolaou, K. C. and Sasmal, Pradip K. and Koftis, Theocharis V. and Converso, Antonella and Loizidou, Erika and Kaiser, Florian and Roecker, A. J. and Dellios, Constantinos C. and Sun, Xiao-Wen and Petrovic, Goran (2005) Studies toward the synthesis of azadirachtin, part 2 : construction of fully functionalized ABCD ring frameworks and unusual intramolecular reactions induced by close-proximity effects. Angewandte Chemie International Edition, 44 (22). pp. 3447-3452. ISSN 1433-7851

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Abstract

The remarkable antifeedant agent and insecticide, azadirachtin (1), has, to date, escaped a total synthesis. The preparation of an advanced precursor has revealed some of the inner intricacies of this uniquely crowded and highly functionalized molecular architecture.

Item Type: Article
Research Areas: A. > School of Science and Technology > Natural Sciences
Item ID: 14365
Depositing User: Erika Loizidou
Date Deposited: 06 Mar 2015 10:11
Last Modified: 13 Oct 2016 14:32
URI: http://eprints.mdx.ac.uk/id/eprint/14365

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